This study reported the activity of catalysts synthesized from platinum and molybdenum alloys in different atomic ratios and used as cathode electrocatalysts in the PEMFC. The structural properties of PtMo/C and Pt/C catalysts were analyzed by XRD analysis. The composition and distribution of these alloys in Vulcan XC-72R Carbon were determined by SEM and EDX techniques. CV studies assessed electrochemical properties such as ORR and ECSA activity. The performance of PEMFC cathodes that supplied pure hydrogen and oxygen was examined using polarization curves at different temperatures. Another way to improve the cathodic reaction is to use ozone as a potent oxidizing agent. It was measured that the OCV of the H2/O3 PEM fuel cell was 1.60 V, much greater than the open circuit voltage of the traditional H2/O2 PEM fuel cell. The PtMo/C catalyst achieved its highest power density of 137 mWcm−2 at 70 °C, 128 mWcm−2 at 60 °C, 101 mWcm−2 at 50 °C, and 85 mWcm−2 at 40 °C when exposed to H2/O2. As the temperature of the cell was raised, it was seen that the catalyst's catalytic activity increased.The maximum power density was detected to be inversely related to the rise in temperature when ozone was used. At low current densities, however, ozone was observed to greatly boost activation polarization. 相似文献
Due to the orientation feature of diffusion tensor images (DTI), tensors need to be reoriented during an affine registration. There exists two active reorientation schemes: finite strain (FS) and preserving principal direction (PPD). However, FS scheme limits its application on rigid deformation and PPD scheme suffers from computation load caused by the iteration. In order to overcome these shortcomings, we propose a canonical form-based affine registration of DTI, named as CFARD. We transform voxel sets into canonical forms where an affine registration is simplified as a rigid registration, while still preserves the effects of non-rigid components. This transforming thus extends the application of FS scheme to affine deformation. Furthermore, to reduce computation load, the quaternion technique is skillfully employed to seek a closed-form solution of the optimal rotation where no iteration is required. Extensive experiments are conducted on synthetic and real DTI data from the human brain. In contrast to four existing algorithms, the proposed CFARD improves the consistency between tensor orientation and the anatomical structures after deformation, and performs a better balance between accuracy and computational complexity.
Hydrogen production from rice husk was carried out via a two-stage system combining CLG (calcium looping gasification) using Ca(OH)2 adsorbent in a bubbling fluidized bed and catalytic reforming with Ce–Ni/γAl2O3 catalyst in a connected fixed bed. The results show that the maximum H2 concentration (69.16 vol%) and H2 yield (11.86 mmol g−1rice husk) are achieved at Ca/C (Ca(OH)2 to carbon molar ratio) = 1.5, H2O/C (H2O to carbon molar ratio) = 1.5, Tg (gasification temperature) = 500 °C, Tc (catalytic temperature) = 800 °C. The supplementation of fresh Ca(OH)2 at Ca/C of 0.5 during calcination helps to activate the regenerated CaO by hydration, maintaining its carbonation activity and CO2 adsorption. Ce–Ni/γAl2O3 catalyst promotes water gas shift (WGS), steam methane reforming (SMR), and C2–C3 hydrocarbons reforming, also exhibits excellent activity stability to maintain H2 concentration and H2 yield above 67.21 vol% and 11.67 mmol g−1rice husk, respectively, during 5 lifetime tests. 相似文献